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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by kephra on Today at 07:14:04 PM »
Stirring certainly helps, and current also if you are having turbidity. 
All other conditions being equal, the size of your anode determines the maximum current you can run without causing turbidity.  A given current produces X amount of silver ions regardless of anode size, but the concentration of silver ions is governed by the volume of the boundary layer which by definition is area times depth of the boundary.  So more area decreases the concentration of silver ions inside the boundary volume.

A long time ago, I tried soluble starch, but all I made was pancake dough. 

I think your best bet is to try something like your rice syrup, tune it to your setup, and then always buy the same brand.
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by aquataur on Today at 06:14:59 PM »
Maltodextrin with a DE rating of 20 higher is officially glucose syrup.   
This explains why maltodextrin DE values end with "19". Our shops have 6,12,19. You guys from the states have a mix.

Turbidity is mainly caused by producing silver ions faster than reducing them.

Does stirring help here? A smaller current?

...there should be no fructose in the resulting sugars.  Fructose can be made from other sugars by adding the correct enzymes, but it does not happen unintentionally.

The sparse analysis values of the above mentioned rice syrups frequently mention a residual amount of fructose, "practically fructose free" for those who must avoid it. I concluded that this is part of an incomplete process, but maybe this stems from "contamination" and cannot be avoided in those big factories.

Colloidal Silver is considered oligodynamic meaning small but powerful.
;D Yeah!

BTW, today I stumbled over a scientific paper (and I found quite an amount of others) quoting that although starch does technically belong to the reducing sugars, it is by all practical means an abysmal one. However, it appears an excellent capping agent.

FYI: High conversion synthesis of <10 nm starch-stabilized silver nanoparticles using microwave technology
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by kephra on Today at 04:49:04 PM »
...
I have researched quite a lot because this whole sweet thing is very confusing. The major confusion arises from sellers putting all that in one pot literally and calling it all glucose syrup.
I found that Glucose is the term used by medicals, dextrose is a technical term. Glucose is NOT glucose syrup. Dried glucose syrup is NOT glucose.
Not any two glucose syrups are equal dependent on the mix of sugars, resulting in a DE value theoretically between 0 and 100 (=pure dextrose).
There is a specific definition of glucose syrup.  Maltodextrin with a DE rating of 20 higher is officially glucose syrup.   
Glucose and dextrose are exactly the same.  The dextrose name comes from the physical property of glucose to rotate the polarization of light to the right.  Fructose, also called levulose, rotates light to the left.  The prefixes are from the latin: Dexter/dextro=right, Laevo/levo=left.
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From what I gather from fellow forumites, maltose heavy syrups appear "slower" in their reduction job. I don´t know if this is directly connected to less turbidity and stronger stabilization.
What appears to be may not actually be.  From observations, we cannot tell the actual speed of reduction.  What we can observe is the speed of color formation.  It is quite possible that the stabilization power of the reducing agent affects color formation by slowing down the building of the nanoparticle from individual atoms.  When making high ppm Colloidal Silver with gelatin and karo, no color really develops until the ppm has far exceeded 20 ppm.  With karo in the water as the reducer, color development should be the same as without gelatin up to 20ppm at least.

Turbidity is mainly caused by producing silver ions faster than reducing them.  This exceeds the solubility limit of silver oxide which then precipitates into insoluble crystals large enough to reflect light and small enough to remain suspended for a considerable time.  The place this happens is in the boundary layer between the anode and bulk water.  This is where voltage is important, as its the electric field which pulls silver ions out of the boundary layer into the bulk water where there is more reducing agent.  Everything is an interplay between a multitude of factors.  Nothing really exists in isolation.  I have always tried to provide guidelines to get people past the major obstacles to good Colloidal Silver.
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Kephra´s analysis does not mention it, but there ought to be traces of fructose (maybe it was not asked for). Also,  there ought to be traces of oligosaccharides.
All of these glucose and corn syrups are made by breaking down starch.  Starch has no fructose, so there should be no fructose in the resulting sugars.  Fructose can be made from other sugars by adding the correct enzymes, but it does not happen unintentionally.

Oligosaccharides simply means small sugar chains, usually defined as 3 to 6.  This includes high DE equivalent maltodextrins.  Speaking of oligo... Colloidal Silver is considered oligodynamic meaning small but powerful.
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by aquataur on Today at 12:09:36 PM »
Gene-ious.

I have researched quite a lot because this whole sweet thing is very confusing. The major confusion arises from sellers putting all that in one pot literally and calling it all glucose syrup.
I found that Glucose is the term used by medicals, dextrose is a technical term. Glucose is NOT glucose syrup. Dried glucose syrup is NOT glucose.
Not any two glucose syrups are equal dependent on the mix of sugars, resulting in a DE value theoretically between 0 and 100 (=pure dextrose).

From what I gather from fellow forumites, maltose heavy syrups appear "slower" in their reduction job. I don´t know if this is directly connected to less turbidity and stronger stabilization.
If that were so, this would certainly explain the increase in stabilization capability beginning with glucose, via Karo to maltodextrin.
In fact, it may be down to the maltose content. Karo has about equal amounts of glucose and maltose, maltodextrin probably more. Malto´s lower DE value would indicate the same, as you mentioned in one of the threads I started (less sweetening).

Dextrose is for some reason called "reiner Traubenzucker", suggesting it were derived from grapes which it is not (but maybe was once). This is for the record for all German readers: beware of all sorts of "Dextro Energen" which contain a gazillion of embellishments. Look for "Dextropur: Reiner Traubenzucker", because they all look damned similar.). But this is readily available in all shops.

The closest syrup stuff to Karo  I found here is rice-syrup. They do of course vary in composition across the brands, but they all appear to be quite maltose-heavy and practically free of fructose.

Kephra´s analysis does not mention it, but there ought to be traces of fructose (maybe it was not asked for). Also,  there ought to be traces of oligosaccharides.

I bought a bottle of it cheap and give it a shot.

Re darker color: I noticed that, but I had read the warnings.
What is turbidity indicative for, incomplete reduction, big particle size? I try to avoid it anyway.

If maltodextrin works for all strenghts, then that is the way to go, although, as you mentioned somewhere, you probably have an inpredictable DE value. But the excess will cope for that.
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by Gene on Yesterday at 10:11:28 PM »
Glucose (mg):   PPM * <liters> * 0.8335

That was the last formula I saw talked about on the forum.

Glucose (dextrose in food use - it has 2 names, same sugar) is a VERY powerful reducer which is why you don't need much.

Some here have had success with it. Myself? I always get a cloudy result no matter what I do and hence I've abandoned using it in favor of Karo for all things other than higher PPM non-gelcapped where I use maltodextrin.

If you have a home beer/winemaking supply shop somewhere near you, give them a call. I bet they have both dextrose powder and maltodextrin powder.  I live in the US but thats where I got mine from and it was inexpensive - around $3/pound (454g) for either. OK, that was maybe 5 years ago (a pound is a damn near lifetime supply unless you're making swimming pools full of the stuff - wink) but it couldn't have gone up THAT much over the years.

The supply shop I got mine from know the stuff as dextrose (probably because thats the common name for food use).  I mentioned glucose and they didn't have a clue other than the glucose syrup they sold (which isn't suitable for Colloidal Silver making - from what I've gleaned, its makup varies).

Malto is used in beer brewing to impart a creamy mouthfeel to the beer so they'd definitely have it.  I'm not sure what the use for dextrose is but given they sell it, its for sure used in either beer brewing or winemaking.

Just one warning. IF you choose to use maltodextrin, your resulting Colloidal Silver will have a slightly (but perceptible) darker yellow color to it at 20PPM (tending towards almost a ruby color at high concentrations up around 80PPM or more).  Reason being, the malto chains (where each only has one reducing group which can only reduce one molecule of silver oxide - ionic silver) are longer and as such you need a lot more of it to get the number of reducing groups necessary to properly reduce the PPM you're making. As such, more "stuff" in solution changes light refraction and maybe other similar characteristics and it pushes the color to a deeper one.

If you're worried after making a batch of higher PPM, dilute a little down to 20PPM and have a gander. If its a little darker (or if you prefer a slightly deeper yellow color) than what you normally get with other reducers, you're good (wink).
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by kephra on Yesterday at 10:04:15 PM »
I believe it will work ok.
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Actually, I get the feeling that the quest for finding the local syrup leads nowhere.
All reducing sugars and non-sugar agents will serve.
...
I never had good luck with pure glucose.  It always lead to a lot of turbidity for me. It has the least stabilizing power.  Better to use maltodextrin which is a better stabilizer, or mix glucose and maltodextrin together.  Syrups are always a combination of at least two sugars which is what keeps them from crystallizing (The molecules have different shapes keeping them from fitting together into a cyrstal).  Our British members use Golden syrup I believe. 

If you want to try pure glucose, I suggest mixing 10 grams in 100 ml of 50/50 mix of water and vodka.  Then use it like corn syrup.  Nothing ventured, nothing gained :) 
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Colloidal Silver Production / Re: Karo Corn Syrup Chemical Analysis
« Last post by aquataur on Yesterday at 09:33:39 PM »
I believe it will work ok.
Actually, I get the feeling that the quest for finding the local syrup leads nowhere.
All reducing sugars and non-sugar agents will serve.

The only problem that may arise is if using too little due to a lower DE value.

That said, I found a source for pure dextrose (powdered). To prevent making a refreshing beverage, how would I calculate a suitable amount? There is much less product variation in a pure product than in all sorts of syrups (which apprear all a mix of at least two sugar types to prevent crystallization), let alone maltodextrin. Dextrose powder is practically DE-100.

If I had no other reference then I would just scale down with increasing DE number. Such as using 1/2 with DE=100 compared to a corn syrup which will be in the DE-40 range.

But then the syrup contains water vs. dry matter - aargh. I admit that all the Moles and atomic weights are a bit over my head.

I appreciate your opinion.


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Colloidal Silver Production / Re: The metallic taste
« Last post by aquataur on Yesterday at 09:21:18 PM »
You can't convince everyone, some people just have no understanding.

I learned this the hard way during the past three years. Telling from myself, I thought somebody would recognize a fact if it was smashing them right in the face.
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Colloidal Silver Production / Re: The metallic taste
« Last post by kephra on Yesterday at 08:33:56 PM »
Metallic has no taste.  What does a silver spoon taste like?  What does a stainless steel spoon taste like?  What does a coin taste like?

Then what does salt taste like, or baking soda, or vinegar.... all ionic substance have a distinctive taste, likewise ionic silver.  This is because they are chemically reactive and react with the chemicals in the taste buds.

You can't convince everyone, some people just have no understanding. 
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Colloidal Silver Production / The metallic taste
« Last post by aquataur on Yesterday at 06:26:21 PM »
I have tried to explain somebody, that they cannot make Colloidal Silver, let alone Gold with empty DW, and I was told, that I probably don't understand the mechanism ::)

The dreaded metallic taste has been referenced here a thousand times. How can you explain that to somebody?
Everybody knows bitter OK.

Where does the bitterness and the taste we associate with metallic come from? I know that touching brass leaves a similar smell on the fingers, and all remind me of garlic, so I suspect sulfur compounds being created in contact with the mouth's tissues.

This would be a striking argument.
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