PLA is actually an organic plastic made from CORN. Yes, that funny yellow stuff that comes on long ears (wink) - at least some constituent part of it.
PLA == PolyLactic Acid
Its supposed to be biodegradable though I doubt seriously if you spit on it it will dissolve right before your eyes (wink). I'd think the concern would be it biodegrading gracefully in a landfill over 5-10-20 years.
You CAN get OTHER plastic filament but how you print with it, speed,... differs (as is to be expected). I don't know, since I don't own a 3d printer, if any of the filament is considered food safe so someone is going to have to look. I can't see how PLA wouldn't be given the source but stranger things have happened.
What I'm going to do (you'd laugh if you saw my electrode holder right now - gotta put a picture of that up some day for posterity) is take a 1/2" HDPE disc I have left over from hole sawing a hole in a bigger piece. I'm going to mark a few different rings on it that coincide with the diameters of a couple different size jars I use on occasion. I'm going to take a dremel tool with a ball end milling bit in it and carefully make a 1/4" or even 5/16" deep channel following each circle so it'll fit on the various jars. Then I'll drill some holes, put electrode holders in that are adjustable and I'm good for the long haul for next to nothing in cost.
People always look at me like "you're saving THAT? Why?". Oh boy, let me tell you (wink). Without fail you need it the day AFTER you toss it. We've all been there.